Cloud Point Extraction With Triton X-114 for Separation of Metsulfuron-Methyl, Chlorsulfuron, and Bensulfuron-Methyl From Water, Soil, and Rice and Analysis by High-Performance Liquid Chromatography.

Summary of "Cloud Point Extraction With Triton X-114 for Separation of Metsulfuron-Methyl, Chlorsulfuron, and Bensulfuron-Methyl From Water, Soil, and Rice and Analysis by High-Performance Liquid Chromatography."

A new and efficient analytic methodology based on cloud point extraction (CPE) was developed for determination of pesticide residues of metsulfuron-methyl (MSM), chlorsulfuron (CS), and bensulfuron-methyl (BSM) in water, soil, and rice grain by high-performance liquid chromatography (HPLC). Multiple experimental conditions that affected CPE efficiency-including surfactant type and concentration, equilibration temperature and duration, ionic strength, and solution pH were identified. CPE conditions were optimized as follows: 1.5% Triton X-114 (w/v), 12% Na(2)SO(4) (w/v) solution (pH 2.0), and heat-assisted at 50°C for 15 min. The calibration curves for all analytes were linear, ranging from 0.05 to 4.0 mg L(-1), with the correlation coefficients >0.9995 by HPLC-ultraviolet detector and were linear, ranging from 0.004 to 2.0 mg L(-1), with correlation coefficients >0.9983 by CPE-HPLC. The average recoveries at the three spiked levels using CPE ranged from 86.0% to 94.5% for water samples with relative SDs (RSDs) of 0.4% to approximately 7.8%; from 85.6% to 94.8% for soil samples with RSDs of 1.2% to approximately 9.5%; and from 81.9% to 91.3% for rice samples with RSDs of 1.7% to approximately 5.8%. The proposed CPE-HPLC method can be successfully used to analyze MSM, CS, and BSM residues from contaminated water, soil, and rice grain samples.


Jiangsu Key Laboratory of Pesticide Science, College of Science, Nanjing Agricultural University, Nanjing, 210095, China.

Journal Details

This article was published in the following journal.

Name: Archives of environmental contamination and toxicology
ISSN: 1432-0703


DeepDyve research library

PubMed Articles [8500 Associated PubMed Articles listed on BioPortfolio]

A new dispersive liquid-liquid microextraction using ionic liquid based microemulsion coupled with cloud point extraction for determination of copper in serum and water samples.

A simple and rapid dispersive liquid-liquid microextraction procedure based on ionic liquid assisted microemulsion (IL-µE-DLLME) combined with cloud point extraction has been developed for preconcent...

Cloud point extraction and gas chromatography with direct microvial insert thermal desorption for the determination of haloanisoles in alcoholic beverages.

A sensitive analytical procedure for the determination of four haloanisoles (2,4,6 trichloroanisole, 2,4,6-tribromoanisole, 2,3,4,6-tetrachloroanisole and pentachloroanisole) related with cork taint d...

Separation/preconcentration of ultra-trace levels of inorganic Sb and Se from different sample matrices by charge transfer sensitized ion-pairing using ultrasonic-assisted cloud point extraction prior to their speciation and determination by hydride generation AAS.

In the existing study, a new, simple and low cost process for separation/preconcentration of ultra-trace level of inorganic Sb and Se from natural waters, beverages and foods using ultrasonic-assisted...

Analysis of N-Glycosylation of Total Membrane Proteins.

Glycosylation of membrane proteins plays a crucial role in various physiological events, including intercellular recognition and intermolecular interactions on the cell surface (Gornik et al., Biochim...

Determination of trace uranium by resonance fluorescence method coupled with photo-catalytic technology and dual cloud point extraction.

In this paper, two kinds of salophens (Sal) with different solubilities, Sal1 and Sal2, have been respectively synthesized, and they all can combine with uranyl to form stable complexes: [UO2(2+)-Sal1...

Clinical Trials [1115 Associated Clinical Trials listed on BioPortfolio]

Comparing Blood Loss During Caesarean Section Between Manual Separation of Placenta & Conservative Management

to compare the blood loss during caesarean section between two different methods of separating the placenta after fetal extraction, keeping in mind that most blood loss occurs after placen...

3D Radiographic Evaluation of a Novel Implant Site Development Technique

The present retrospective study aims at assessing the clinical effects of a novel implant site development (Extraction site development - XSD) technique after tooth extraction compared wit...

TAFF-Psychological Treatment of Separation Anxiety Disorder

The purpose of this study is to determine whether a specific family based cognitive behavioral treatment program is effective in the treatment of children with separation anxiety disorder.

Periodontal Phenotype Study

The purpose of this trial is to determine the correlations between various tissue dimensions and the changes that occur following a single-tooth dental extraction in human adults. 65 adul...

Se-Methyl-Seleno-L-Cysteine or Selenomethionine in Preventing Prostate Cancer in Healthy Participants

This randomized phase I trial studies the side effects and the best dose of Se-methyl-seleno-L-cysteine or selenomethionine in preventing prostate cancer in healthy participants. Chemoprev...

Medical and Biotech [MESH] Definitions

Use of various chemical separation and extraction methods, such as SOLID PHASE EXTRACTION; CHROMATOGRAPHY; and SUPERCRITICAL FLUID EXTRACTION; to prepare samples for analytical measurement of components.

The length of the face determined by the distance of separation of jaws. Occlusal vertical dimension (OVD or VDO) or contact vertical dimension is the lower face height with the teeth in centric occlusion. Rest vertical dimension (VDR) is the lower face height measured from a chin point to a point just below the nose, with the mandible in rest position. (From Jablonski, Dictionary of Dentistry, 1992, p250)

The selective extraction of deciduous teeth during the stage of mixed dentition in accordance with the shedding and eruption of the teeth. It is done over an extended period to allow autonomous adjustment to relieve crowding of the dental arches during the eruption of the lateral incisors, canines, and premolars, eventually involving the extraction of the first premolar teeth. (Dorland, 28th ed)

The separation of individuals or groups resulting in the lack of or minimizing of social contact and/or communication. This separation may be accomplished by physical separation, by social barriers and by psychological mechanisms. In the latter, there may be interaction but no real communication.

The separation of particles from a suspension by passage through a filter with very fine pores. In ultrafiltration the separation is accomplished by convective transport; in DIALYSIS separation relies instead upon differential diffusion. Ultrafiltration occurs naturally and is a laboratory procedure. Artificial ultrafiltration of the blood is referred to as HEMOFILTRATION or HEMODIAFILTRATION (if combined with HEMODIALYSIS).

Quick Search

DeepDyve research library

Searches Linking to this Article