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Ordered iron oxide ultrathin films were fabricated on a single-crystal Mo(110) substrate under ultrahigh vacuum conditions by either depositing Fe in ambient oxygen or oxidizing preprepared Fe(110) films. The surface structure and electronic structure of the iron oxide films were investigated by various surface analytical techniques. The results indicate surface structural transformations from metastable FeO(111) and O-terminated Fe(2)O(3)(0001) to Fe(3)O(4)(111) films, respectively. The former depends strongly on the oxygen pressure and substrate temperature, and the latter relies mostly upon the annealing temperature. Our experimental observations are helpful in understanding the mechanisms of surface structural evolution in iron oxides. The model surfaces of Fe-oxide films, particularly O-terminated surfaces, can be used for further investigation in chemical reactions (e.g., in catalysis).
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100190, PR China.
This article was published in the following journal.
Name: Langmuir : the ACS journal of surfaces and colloids
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The techniques used to produce molecules exhibiting properties that conform to the demands of the experimenter. These techniques combine methods of generating structural changes with methods of selection. They are also used to examine proposed mechanisms of evolution under in vitro selection conditions.
Iron or iron compounds used in foods or as food. Dietary iron is important in oxygen transport and the synthesis of the iron-porphyrin proteins hemoglobin, myoglobin, cytochromes, and cytochrome oxidase. Insufficient amounts of dietary iron can lead to iron-deficiency anemia.
Membrane glycoproteins found in high concentrations on iron-utilizing cells. They specifically bind iron-bearing transferrin, are endocytosed with its ligand and then returned to the cell surface where transferrin without its iron is released.
Works consisting of nonfiction films and video designed to teach, instruct, or train. (From Moving Image Materials: Genre Terms, 1988)