Copper(ii)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides.
Summary of "Copper(ii)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides."
Copper-catalyzed ortho-benzoxylation of 2-arylpyridine sp(2) C-H bonds with acyl chloride is described. Notably, switching the base from t-BuOK to Li(2)CO(3) causes chlorination of the C-H bond to take place.
College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325000, People's Republic of China. firstname.lastname@example.org email@example.com.
This article was published in the following journal.
Name: Chemical communications (Cambridge, England)
Medical and Biotech [MESH] Definitions
Enoyl-(acyl-carrier-protein) Reductase (nadh)
An NAD-dependent enzyme that catalyzes the oxidation of acyl-[acyl-carrier protein] to trans-2,3-dehydroacyl-[acyl-carrier protein]. It has a preference for acyl groups with a carbon chain length between 4 to 16.
Enoyl-(acyl-carrier Protein) Reductase (nadph, B-specific)
An enzyme that catalyzes the oxidation of acyl-[acyl-carrier protein] to trans-2,3-dehydroacyl-[acyl-carrier protein] in the fatty acid biosynthesis pathway. It has a preference for acyl derivatives with carbon chain length from 4 to 16.
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An enzyme of long-chain fatty acid synthesis, that adds a two-carbon unit from malonyl-(acyl carrier protein) to another molecule of fatty acyl-(acyl carrier protein), giving a beta-ketoacyl-(acyl carrier protein) with the release of carbon dioxide. EC 220.127.116.11.
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