Advertisement

Topics

Two Finite Binuclear M2(μ2-OH)(COO)2 (M = Co, Ni) Based Highly Porous Metal-Organic Frameworks with High Performance for Gas Sorption and Separation.

08:00 EDT 17th March 2017 | BioPortfolio

Summary of "Two Finite Binuclear M2(μ2-OH)(COO)2 (M = Co, Ni) Based Highly Porous Metal-Organic Frameworks with High Performance for Gas Sorption and Separation."

Two highly porous MOFs, [Co2(μ2-OH)(bpdc)(Htpim)2][SiF6]·3.5DMA·2.5CH3OH (JLU-Liu37, H2bpdc = biphenyl-4,4'-dicarboxylate, Htpim = 2,4,5-tri(4-pyridyl)imidazole) and [Ni2(μ2-OH)(bpdc)(Htpim)2][SiF6]·7.5DMA·6CH3OH (JLU-Liu38), have been solvothermally synthesized by using the mixed ligand strategy. Both of the compounds possess finite binuclear [M2(μ2-OH)(COO)2] (M = Co, Ni) secondary building units (SBUs) which formed with a polar functional group, μ2-OH. JLU-Liu37 and JLU-Liu38 exhibit notable adsorption capacities for CO2 and light hydrocarbons (CH4, C2H6, and C3H8). Moreover, both of the materials exhibit arrestive natural gas selective separation ability, especially for C3H8/CH4 (206 for an equimolar mixture under 1 bar and 298 K, for JLU-Liu37). Both of the MOFs may be effectively applied in the separation of industrial light hydrocarbons.

Affiliation

Journal Details

This article was published in the following journal.

Name: Inorganic chemistry
ISSN: 1520-510X
Pages:

Links

DeepDyve research library

PubMed Articles [28754 Associated PubMed Articles listed on BioPortfolio]

Boron Functionalized Graphene-Organic Frameworks for Highly Efficient CO2 Capture.

The capture and storage of CO2 have been suggested as an effective strategy to reduce the global emissions of greenhouse gases. Hence, in recent years, many research has been carried out to develop hi...

Facile Synthesis of Metal-Loaded Porous Carbon Thin Films via Carbonization of Surface-Mounted Metal-Organic Frameworks.

We report a facile approach to prepare metal-nanocatalyst-incorporated carbon thin films with uniform size distribution via carbonization of surface-mounted metal-organic frameworks (SURMOFs) and meta...

Bicyclo2.2.2octane-1,4-dicarboxylic acid: towards transparent metal-organic frameworks.

The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal-organic frameworks represent a unique opportunity due to t...

Accurate van der Waals force field for gas adsorption in porous materials.

An accurate van der Waals force field (VDW FF) was derived from highly precise quantum mechanical (QM) calculations. Small molecular clusters were used to explore van der Waals interactions between ga...

A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability.

The pore size enlargement and structural stability have been recognized as two crucial targets, which are rarely achieved together, in the development of metal-organic frameworks (MOFs). Herein, we ha...

Clinical Trials [3183 Associated Clinical Trials listed on BioPortfolio]

Roentgen Stereophotogrammetric Analysis (RSA) to Evaluate Fixation of Biofoam Advance Total Knee Arthroplasty Components

Hip and knee replacement arthroplasty are profoundly successful operative interventions, however, some joint replacements do fail and the life expectancy of a hip or knee arthroplasty is f...

Uncemented Tritanium Compared With Cemented Metal-backed Tibia Components in Total Knee Replacement

The optimal method of total knee replacement component fixation to the bone remains a challenge. The use of bone cement is considered the gold standard and is the preferred technique for m...

Reconstruction Implant Bone After Removal Using Porous Titanium Prosthesis

This trial will study the reconstruction of the anterior part of the mandible and the adjacent soft tissue parts by a mandibular prosthesis made in porous titanium, associated or not, to a...

Metal Ion Release From an FDA-Approved Metal-on-Metal Total Hip Replacement Implant

This is a multi-center, randomized study to compare blood and urine cobalt, chromium, and titanium ion levels of a metal-on-metal articular bearing coupled with two different head sizes to...

A Multicentre Trial to Compare Two Articulating Bearing Surfaces as Used in Cementless Primary Hip Arthroplasty

The aim of this study is to demonstrate the non-inferiority of the ceramic-on-metal articulation using large diameter bearings (38mm to 60mm) compared to the metal on metal articulation us...

Medical and Biotech [MESH] Definitions

Polymer of polytetrafluoroethylene and carbon filaments; porous biocompatible material used in orofacial and middle ear reconstruction and as coating for metal implants.

A computer based method of simulating or analyzing the behavior of structures or components.

Organic polymeric materials which can be broken down by naturally occurring processes. This includes plastics created from bio-based or petrochemical-based materials.

The fusion of ceramics (porcelain) to an alloy of two or more metals for use in restorative and prosthodontic dentistry. Examples of metal alloys employed include cobalt-chromium, gold-palladium, gold-platinum-palladium, and nickel-based alloys.

Techniques used to separate mixtures of substances based on differences in the relative affinities of the substances for mobile and stationary phases. A mobile phase (fluid or gas) passes through a column containing a stationary phase of porous solid or liquid coated on a solid support. Usage is both analytical for small amounts and preparative for bulk amounts.

Quick Search
Advertisement
 


DeepDyve research library

Searches Linking to this Article