Advertisement

Topics

Enhanced Catalytic Activity of Sub-nanometer Titania Clusters Confined inside Double-Wall Carbon Nanotubes.

Summary of "Enhanced Catalytic Activity of Sub-nanometer Titania Clusters Confined inside Double-Wall Carbon Nanotubes."

Sub-nanometer titania clusters have been homogeneously dispersed within double-wall carbon nantubes (DWNTs) with an inner diameter ranging from 1.0 to 1.5 nm. The confined titania exhibits a much higher activity than the titania particles attached on the outside walls of the DWNTs (the outside titania) in the epoxidation of propylene by H(2) O(2) . XPS, XANES and Raman spectroscopy data suggest electron transfer from titanium to the inner surfaces of the DWNTs. In contrast, no electron transfer has been observed for the outside titania. We also found that the extent of this confinement-induced electron transfer is temperature dependent. The enhanced activity of the confined titania clusters is likely attributed to their small sizes and the interaction with the DWNT surface. The synthesis method that we developed here can be readily applied to incorporation of other metal/metal oxide nanoparticles into carbon nanotubes.

Affiliation

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, the Chinese Academy of Sciences, Zhongshan Road 457, Dalian 116023 (PR China), Fax: (+86) 411 8469 4447.

Journal Details

This article was published in the following journal.

Name: ChemSusChem
ISSN: 1864-564X
Pages: 975-80

Links

DeepDyve research library

PubMed Articles [19889 Associated PubMed Articles listed on BioPortfolio]

Ti(3+) Promoted High Oxygen-reduction Activity of Pd Nanodots Supported by Black Titania Nanobelts.

One-dimensional nanocrystals favoring efficient charge transfer have attracted enormous attentions, and conductive nanobelts of black titania with a unique band structure and high electrical conductiv...

Theophylline-assisted, eco-friendly synthesis of PtAu nanospheres at reduced graphene oxide with enhanced catalytic activity towards Cr(VI) reduction.

Theophylline as a naturally alkaloid is commonly employed to treat asthma and chronic obstructive pulmonary disorder. Herein, a facile theophylline-assisted green approach was firstly developed for sy...

Water Oxidation by Size-Selected Co27 Clusters Supported on Fe2 O3.

The complexity of the water oxidation reaction makes understanding the role of individual catalytic sites critical to improving the process. Here, size-selected 27-atom cobalt clusters (Co27 ) deposit...

Controllable reduced black titania with enhanced photoelectrochemical water splitting performance.

Black titania prepared by metal-reduction methods is systematically studied and found the best controllable Mg-reduction method. Colored titania products from white, light blue, dark blue, to black we...

Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D.

Single metal atoms and metal clusters have attracted much attention thanks to their advantageous capabilities as heterogeneous catalysts. However, the generation of stable single atoms and clusters on...

Clinical Trials [3309 Associated Clinical Trials listed on BioPortfolio]

Catalytic Antibodies and Lupus in Martinique

- The Martinique island (French West-Indies) is an area of high prevalence and incidence for Systemic Lupus Erythematosus (SLE), respectively 64,2/ 100000 and 4,7/ 100000. In ma...

Patient Comfort Using Green vs. Yellow Pan Retinal Photocoagulation

Our aim is to compare patient comfort when using the 532 nanometer (green) wavelength laser to the 577 nanometer (yellow) wavelength laser during pan retinal photocoagulation to treat pati...

CoQ10 and Prednisone in Non-Ambulatory DMD

This study will help determine if CoQ10 and prednisone, alone and as a combination decrease the decline in cardiopulmonary and skeletal muscle function that occurs in the wheelchair confin...

Cooperative Pain Education and Self-management

This study will test the effectiveness of using enhanced facilitation strategies on implementation of an automated Interactive Voice Response (IVR) system as a means to remotely deliver in...

Dried Fruit and Postprandial Glycemia Trial

Dried fruits show promising potential for the management of blood glucose. Previous trials have reported beneficial effects of raisins on post-prandial glucose and insulin responses in hea...

Medical and Biotech [MESH] Definitions

RNA that has catalytic activity. The catalytic RNA sequence folds to form a complex surface that can function as an enzyme in reactions with itself and other molecules. It may function even in the absence of protein. There are numerous examples of RNA species that are acted upon by catalytic RNA, however the scope of this enzyme class is not limited to a particular type of substrate.

Biological molecules that possess catalytic activity. They may occur naturally or be synthetically created. Enzymes are usually proteins, however CATALYTIC RNA and CATALYTIC DNA molecules have also been identified.

A malignancy arising in uterine cervical epithelium and confined thereto, representing a continuum of histological changes ranging from well-differentiated CIN 1 (formerly, mild dysplasia) to severe dysplasia/carcinoma in situ, CIN 3. The lesion arises at the squamocolumnar cell junction at the transformation zone of the endocervical canal, with a variable tendency to develop invasive epidermoid carcinoma, a tendency that is enhanced by concomitant human papillomaviral infection. (Segen, Dictionary of Modern Medicine, 1992)

Molecules of DNA that possess enzymatic activity.

Inherited conditions characterized by the partial loss of ADIPOSE TISSUE, either confined to the extremities with normal or increased fat deposits on the face, neck and trunk (type 1), or confined to the loss of SUBCUTANEOUS FAT from the limbs and trunk (type 2).

Quick Search
Advertisement
 


DeepDyve research library

Searches Linking to this Article