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An array of surface science measurements has revealed novel water adsorption behavior at the Fe(3)O(4)(001) surface. Following room temperature exposure to water, a low coverage of hydrogen atoms is observed, with no associated water hydroxyl group. Mild annealing of the hydrogenated surface leads to desorption of water via abstraction of surface oxygen atoms, leading to a reduction of the surface. These results point to an irreversible splitting of the water molecule. The observed phenomena are discussed in the context of recent DFT calculations ( Mulakaluri , N. ; Pentcheva , R. ; Scheffler , M. J. Phys. Chem. C 2010 , 114 , 11148 ), which show that the Jahn-Teller distorted surface isolates adsorbed H in a geometry that could kinetically hinder recombinative desorption. In contrast, the adsorption geometry facilitates interaction between water hydroxyl species, which are concluded to leave the surface following a reactive desorption process, possibly via the creation of O(2).
Institute of Applied Physics, Vienna University of Technology , Vienna, Austria.
This article was published in the following journal.
Name: Journal of the American Chemical Society
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The effect of adding Nanobone on horizontal bone gain in ridge splitting.
The TEMPERATURE at the outer surface of the body.
Medicated dosage forms that are designed to be inserted into the rectal, vaginal, or urethral orifice of the body for absorption. Generally, the active ingredients are packaged in dosage forms containing fatty bases such as cocoa butter, hydrogenated oil, or glycerogelatin that are solid at room temperature but melt or dissolve at body temperature.
A surfactant that renders a surface wettable by water or enhances the spreading of water over the surface; used in foods and cosmetics; important in contrast media; also with contact lenses, dentures, and some prostheses. Synonyms: humectants; hydrating agents.
Organic compounds that have a relatively high VAPOR PRESSURE at room temperature.
Circulation of water among various ecological systems, in various states, on, above, and below the surface of the earth.
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