The use of permeation tube device and the development of empirical formula for accurate permeation rate.
Summary of "The use of permeation tube device and the development of empirical formula for accurate permeation rate."
A series of laboratory experiments were conducted to assess the accuracy of permeation tube (PT) devices using a calibration gas generator system to measure permeation rate (PR) of volatile organic compounds (VOCs). Calibration gas standards of benzene, toluene, and m-xylene (BTX) were produced from PTs at varying flow rates (FR) of 20-1200mLmin(-1) and constant temperature (30°C). Results indicate that changes in flow rate greatly affected the permeation rate of each VOC at this temperature. This paper presents experimental approaches to accurately measure actual permeation rate (APR) and the derivation of empirical equations for predicted permeation rate (PPR). If the magnitude of bias is defined as the difference between PPR and the manufacturer's permeation rate (MPR), the bias was typically 19-40% for toluene (T) and 31-54% for m-xylene (X). Benzene (B) exhibited the least bias of 1.4-18.8%, nevertheless our PPR values for benzene were more reliable at lower flow rates (0.75-1.20%). This study highlights the importance of flow rate and associated pressure changes as a key to accurate permeation rate estimation from permeation tube devices.
Department of Environment & Energy, Sejong University, 98 Goon Ja Dong, Seoul 143-747, South Korea.
This article was published in the following journal.
Name: Journal of chromatography. A
- PubMed Source: http://www.ncbi.nlm.nih.gov/pubmed/22129573
- DOI: http://dx.doi.org/10.1016/j.chroma.2011.11.007
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Medical and Biotech [MESH] Definitions
The transparent anterior portion of the fibrous coat of the eye consisting of five layers: stratified squamous CORNEAL EPITHELIUM; BOWMAN MEMBRANE; CORNEAL STROMA; DESCEMET MEMBRANE; and mesenchymal CORNEAL ENDOTHELIUM. It serves as the first refracting medium of the eye. It is structurally continuous with the SCLERA, avascular, receiving its nourishment by permeation through spaces between the lamellae, and is innervated by the ophthalmic division of the TRIGEMINAL NERVE via the ciliary nerves and those of the surrounding conjunctiva which together form plexuses. (Cline et al., Dictionary of Visual Science, 4th ed)
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The removal of secretions, gas or fluid from hollow or tubular organs or cavities by means of a tube and a device that acts on negative pressure.
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The two longitudinal ridges along the PRIMITIVE STREAK appearing near the end of GASTRULATION during development of nervous system (NEURULATION). The ridges are formed by folding of NEURAL PLATE. Between the ridges is a neural groove which deepens as the fold become elevated. When the folds meet at midline, the groove becomes a closed tube, the NEURAL TUBE.