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A new generation of platinum and iodine free efficient dye-sensitized solar cells.

06:44 EDT 24th July 2014 | BioPortfolio

Summary of "A new generation of platinum and iodine free efficient dye-sensitized solar cells."

We report a series of cobalt complexes with various polypyridyl ligands, where the oxidation potential is tuned from 0.17 to 0.34 V vs. ferrocene. The highest occupied molecular orbitals (HOMO) of the cobalt complexes were stabilized by adding electron acceptor groups on pyridyl or replacing pyridyl by pyrazole. These complexes are then used as one-electron redox mediators in dye sensitized solar cells (DSSCs) together with polymer based cathode resulting in an excellent performance. The performance of DSSCs using the molecularly engineered cobalt redox shuttle and poly(3,4-alkylthiophenes) based cathode is better than the triiodide/iodide redox shuttle with platinized cathode. The use of high surface area poly(3,4-propylenedioxythiophene) based nanoporous layers allows higher catalytic activity thus minimizing the electrode-electrolyte interface issues.

Affiliation

Laboratory of Photonics and Interfaces, Department de Chimie, Ecole Polytechnique Federale de Lausanne, CH-1015 Lausanne, Switzerland. mdkhaja.nazeeruddin@epfl.ch.

Journal Details

This article was published in the following journal.

Name: Physical chemistry chemical physics : PCCP
ISSN: 1463-9084
Pages: 10631-9

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Platinum. A heavy, soft, whitish metal, resembling tin, atomic number 78, atomic weight 195.09, symbol Pt. (From Dorland, 28th ed) It is used in manufacturing equipment for laboratory and industrial use. It occurs as a black powder (platinum black) and as a spongy substance (spongy platinum) and may have been known in Pliny's time as "alutiae".

Stable iodine atoms that have the same atomic number as the element iodine, but differ in atomic weight. I-127 is the only naturally occurring stable iodine isotope.

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