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Interaction of anionic surfactant with polymeric nanoparticles of similar charge.

22:12 EDT 23rd May 2013 | BioPortfolio

Summary of "Interaction of anionic surfactant with polymeric nanoparticles of similar charge."

The formation of micelle-like nanosize aggregates above a critical aggregation concentration (CAC) by a water-soluble, amphiphilic, and statistical copolymer poly(SAMPS/DA) of sodium N-acrylamidomethylpropanesulfonate (SAMPS) and N-dodecylacrylamide (DA) was studied. The structural changes that result from the interactions between the polymeric nanoparticles and sodium dodecylsulfate (SDS), an anionic surfactant, were studied with the aid of surface tension, viscosity, steady-state fluorescence, dynamic light scattering, and transmission electron microscopic techniques. In dilute solution with polymer concentration C(p)CAC, strong interactions between the polyelectrolyte and SDS were observed even at a very low level of surfactant addition. The interaction is purely hydrophobic in nature. The surfactant monomers bind to the polymer micelles to form smaller spherical aggregates (polymer-SDS complex). When surfactant was added above its saturation concentration, the association complexes are disrupted and only surfactant micelles decorated by polymer chain(s) were observed. The microenvironment of the polymer-SDS complexes was observed to be much less polar than that of neat polymer aggregates and SDS micelles. Also, the internal rigidity of the polymer-SDS complexes was found to be higher than that of the pure polymer or SDS micelles. It was observed that the neat polymer aggregates and polymer-decorated SDS micelles are more stable than the polymer-SDS complexes.

Affiliation

Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India.

Journal Details

This article was published in the following journal.

Name: Journal of colloid and interface science
ISSN: 1095-7103
Pages:

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Medical and Biotech [MESH] Definitions

Holothurin

A highly toxic saponin occurring in HOLOTHUROIDEA. This marine toxin is an anionic surfactant, hemolyzing ERYTHROCYTES.

Nanoparticles

Nanometer-sized particles that are nanoscale in three dimensions. They include nanocrystaline materials; NANOCAPSULES; METAL NANOPARTICLES; DENDRIMERS, and QUANTUM DOTS. The uses of nanoparticles include DRUG DELIVERY SYSTEMS and cancer targeting and imaging.

Magnetite Nanoparticles

Synthesized magnetic particles under 100 nanometers possessing many biomedical applications including DRUG DELIVERY SYSTEMS and CONTRAST AGENTS. The particles are usually coated with a variety of polymeric compounds.

Ions

An atom or group of atoms that have a positive or negative electric charge due to a gain (negative charge) or loss (positive charge) of one or more electrons. Atoms with a positive charge are known as CATIONS; those with a negative charge are ANIONS.

Sodium Dodecyl Sulfate

An anionic surfactant, usually a mixture of sodium alkyl sulfates, mainly the lauryl; lowers surface tension of aqueous solutions; used as fat emulsifier, wetting agent, detergent in cosmetics, pharmaceuticals and toothpastes; also as research tool in protein biochemistry.

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