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Identification and characterization of three impurities in clocortolone pivalate.

Clocortolone pivalate is a synthetic corticosteroid that can be used to cure corticosteroid-responsive dermatoses. Three previously unknown impurities detected by HPLC were isolated by semi-preparativ...

A short-term high-dose administration of sodium pivalate impairs pyruvate metabolism without affecting cardiac function.

The pivalate moiety of some oral antibiotics enhances their intestinal absorption, but liberated pivalic acid decreases tissue carnitine concentration and could lead to impaired energy metabolism. The...

Lower initial dose desoxycorticosterone pivalate for treatment of canine primary hypoadrenocorticism.

To evaluate the efficacy of initial doses of desoxycorticosterone pivalate (DOCP) that are lower and less expensive than the presently recommended initial dose of 2.2 mg/kg for treating dogs with pr...

Avoiding Magnetochemical Overparametrization, Exemplified by One-Dimensional Chains of Hexanuclear Iron(III) Pivalate Clusters.

One-dimensional chain coordination polymers based on hexanuclear iron(III) pivalate building blocks and 1,4-dioxane (diox) or 4,4'-bipyridine (4,4'-bpy) bridging ligands, [Fe6O2(O2CH2)(O2CCMe3)12(diox...

Autocatalysis for C-H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes.

Kinetic data for the C-H bond activation of 2-phenylpyridine by Ru(II)(carboxylate)(2)(p-cymene) I (acetate) and I' (pivalate) are available for the first time. They reveal an irreversible autocatalyt...