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Ytterbium can relax slowly too: a field-induced Yb(2) single-molecule magnet.

An unusual dinuclear Yb(2) complex isolated using a mixed ligand strategy leads to field-induced SMM behaviour. Low magnetic axiality and a large tunnelling gap lead to significant quantum tunnelling...

An unsymmetrical coordination environment leading to two slow relaxation modes in a Dy(2) single-molecule magnet.

A Dy(2) single-molecule magnet was isolated using a mixed ligand strategy in which the Dy(III) ions adopt distinct coordination environments. This leads to two unique relaxation modes due to a single-...

A novel high-spin tridecanuclear Ni(II) cluster with an azido-bridged core exhibiting disk-like topology.

A high-spin tridecanuclear Ni(II) cluster, [Ni(II)(13)(N(3))(18)(dpo)(4)(Hdpo)(2)(H(2)hpo)(4)(H(2)O)(MeOH)] [Ni(II)(13)(N(3))(18)(dpo)(4)(Hdpo)(2)(H(2)hpo)(4)(H(2)O)(2)] (1) (Hdpo = 1-(dimethylamino)p...

First structural evidence for multiple alkali metals between sandwich decks in a metallocene.

A tetralithio salt (1) derived by treating 1,4-bis(trimethylsilyl)-cyclooctatriene with (n)BuLi serves as the first structural evidence for a multi-alkali metallocene. Single-crystal XRD confirms two...

Synthesis, characterisation and computational studies on a novel one-dimensional arrangement of Schiff-base Mn(3) single-molecule magnet.

The syntheses, structures and magnetic properties are reported for three new manganese complexes containing the Schiff-base ((2-hydroxy-3-methoxyphenyl)methylene)isonicotinohydrazine (H(2)hmi) ligand....