Search Results for "Knoevenagel Condensation Transition State"
Original Source: The catalytic asymmetric knoevenagel condensation.
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Bose glass and Mott glass of quasiparticles in a doped quantum magnet
The low-temperature states of bosonic fluids exhibit fundamental quantum effects at the macroscopic scale: the best-known examples are Bose–Einstein condensation and superfluidity, which have been t...
Low-temperature physics: Cool molecules
A sample of the hydroxyl radical has been cooled to a temperature of a few millikelvin. The result opens the door to observing phenomena such as Bose–Einstein condensation of molecules in their grou...
Cyclization of fungal nonribosomal peptides by a terminal condensation-like domain
The quantum world only partially ‘melts’
Physical systems in the everyday world are constantly striving for thermal equlibrium: ice cubes in hot water, for example. In the transition area from mixed state to thermalized state are intermed...
Role of vacancies in metal–insulator transitions of crystalline phase-change materials
Phase-change materials show an unusual metal–insulator transition that is induced by disorder in the crystalline state. Numerical computations now show how the transition to the metallic state proce...
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Prebiotically plausible oligoribonucleotide ligation facilitated by chemoselective acetylation
One theory for the abiogenesis of RNA involves ligation of shorter oligomers that are observed after dry-state condensation of mononucleotides. Here, the chemo- and regioselective acetylation of (olig...
Quantum-state transfer from an ion to a photon
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Matching PubMed Articles
Ozonolysis of the 2,6-divinyl derivative of a naphthalene diimide (NDI) affords a 2,6-diformyl-NDI, which can be used in Knoevenagel condensation reactions, as demonstrated by the synthesis of a 2,6-b...
A highly negatively charged γ-Keggin germanodecatungstate efficient for Knoevenagel condensation.
A tetra-n-butylammonium (TBA) salt of a γ-Keggin -6-charged germanodecatungstate, [γ-H(2)GeW(10)O(36)](6-) (I), could act as an efficient homogeneous catalyst for Knoevenagel condensation of active...
Diastereoselective one-pot knoevenagel condensation/corey-chaykovsky cyclopropanation.
Efforts to substitute the cyclopropane ring in a series of aryl cyclopropylnitriles led to the discovery of an operationally simple one-pot method for Knoevenagel condensation and subsequent Corey-Cha...
A DFT study of IRMOF-3 catalysed Knoevenagel condensation.
It has been recently reported that IRMOF-3 [Gascon et al., J. Catal, 2009, 261, 75] may behave as a basic catalyst, active in the Knoevenagel condensation. In particular, it has been shown that the ba...
Mechanism of the Organocatalyzed Decarboxylative Knoevenagel-Doebner Reaction. A Theoretical Study.
We have investigated important intermediates and key transition states of the organocatalyzed Knoevenagel condensation using density functional theory and two different basis sets (6-31 G(d,p) and 6-3...