Pressure Dependence of Carbonate Exchange with NpO2(CO3)3(4-) in Aqueous Solutions.

07:00 EST 13th December 2016 | BioPortfolio

Summary of "Pressure Dependence of Carbonate Exchange with NpO2(CO3)3(4-) in Aqueous Solutions."

The rates of ligand exchange into the geochemically important [NpO2(CO3)3](4-) aqueous complex are measured as a function of pressure in order to complement existing data on the isostructural [UO2(CO3)3](4-) complex. Experiments are conducted at pH conditions where the rate of exchange is independent of the proton concentration. Unexpectedly, the experiments show a distinct difference in the pressure dependencies of rates of exchange for the uranyl and neptunyl complexes.


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This article was published in the following journal.

Name: Inorganic chemistry
ISSN: 1520-510X


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