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In this Perspective, we examine the use of laser-cooled atomic ions and sympathetically cooled molecular ions in Coulomb crystals for molecular spectroscopy. Coulomb crystals are well-isolated environments that provide localization and long storage times for sensitive measurements of weak signals and cold temperatures for precise spectroscopy. Coulomb crystals of molecular and atomic ions enable the detection of single photon molecular ion transitions at a range of wavelengths by a change in atomic ion fluorescence at visible wavelengths. We give an overview of the state-of-the-art from action spectroscopy to quantum logic spectroscopy for a wide range of molecular transitions from rotational sublevels separated by 10 cm to rovibronic transitions at 25000 cm. We emphasize how this system allows for unparalleled control of the molecular ion state for precision spectroscopy with applications in astrochemistry and fundamental physics. We conclude with an outlook of the use of this control in cold molecular ion reactions.
This article was published in the following journal.
Name: The journal of physical chemistry letters
The ESEEM spectroscopy was used to determine positions of the Nd impurity ions in YSiO single crystal. It is established that neodymium ions substitute yttrium ions in the Y2 positions with seven near...
Single crystals of potassium magnesium chloride sulfate (KMCS) doped with cobalt ions were grown by slow cooling method. Powder XRD study confirmed the monoclinic structure of the grown crystals. The ...
Dislocations in molecular crystals remain terra incognita. Owing to the complexity of molecular structure, dislocations in molecular crystals can be difficult to understand using only the foundational...
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The study is a 2 arm, multi-center, randomized, open-labeled clinical trial designed to assess the effects of varying doses and schedules of oral insulin on immunological and metabolic mar...
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A mass spectrometric technique that is used for the analysis of large biomolecules. Analyte molecules are embedded in an excess matrix of small organic molecules that show a high resonant absorption at the laser wavelength used. The matrix absorbs the laser energy, thus inducing a soft disintegration of the sample-matrix mixture into free (gas phase) matrix and analyte molecules and molecular ions. In general, only molecular ions of the analyte molecules are produced, and almost no fragmentation occurs. This makes the method well suited for molecular weight determinations and mixture analysis.
Spectroscopy technique which measures changes in organic compounds by tracking the spectral energy of absorption of HYDROGEN atoms.
A spectroscopic technique which uses the Mossbauer effect (inelastic scattering of gamma radiation resulting from interaction with heavy nuclei) to monitor the small variations in the interaction between an atomic nucleus and its environment. Such variations may be induced by changes in temperature, pressure, chemical state, molecular conformation, molecular interaction, or physical site. It is particularly useful for studies of structure-activity relationship in metalloproteins, mobility of heavy metals, and the state of whole tissue and cell membranes.
The internal resistance of a material to moving some parts of it parallel to a fixed plane, in contrast to stretching (TENSILE STRENGTH) or compression (COMPRESSIVE STRENGTH). Ionic crystals are brittle because, when subjected to shear, ions of the same charge are brought next to each other, which causes repulsion.
The movement of ions across energy-transducing cell membranes. Transport can be active, passive or facilitated. Ions may travel by themselves (uniport), or as a group of two or more ions in the same (symport) or opposite (antiport) directions.
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