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Soil is a heterogeneous porous media that is comprised of a variety of organo-mineral aggregates. Sorption of heavy metals onto these composite solids is a key process that controls heavy metal mobility and fate in the natural environment. Pollution from a combination of heavy metals is common in soil, therefore, understanding the competitive binding behavior of metal ions to organo-mineral composites is important in order to predict metal mobility and fate. In this study, batch experiments were paired with spectroscopic studies to probe the sorption characteristics of ternary CdNiCu sorbates to a binary organo-goethite composite made with Bacillus cereus cells. Scanning electron microscopy shows that goethite nano-sized crystals are closely associated with the bacterial surfaces. Sorption experiments show a larger adsorptivity and affinity for Cu than Cd/Ni on goethite and B. cereus, and the goethite-B. cereus composite. X-ray photoelectron spectroscopy reveals that carboxylate and phosphate functional moieties present on the bacterial cell walls are primarily responsible for metal sorption to the goethite-B. cereus composite. Synchrotron-based X-ray fluorescence shows that Cu and Ni are predominately associated with the bacterial fraction of the goethite-B. cereus composite, whereas Cd is mainly associated with the goethite fraction. The findings of this research have important implications for predicting the mobility and fate of heavy metals in soil multi-component systems.
This article was published in the following journal.
Name: Environmental pollution (Barking, Essex : 1987)
Chromate was used as a chemical probe to investigate the impact of mineral-organic contact time on the surface reactivity of two different sizes of goethite particles. A series of goethite-chromate so...
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Goethite-humic acid complex was prepared in a suspension containing goethite and humic acid. X-ray diffraction (XRD) results showed that the crystal structure of this complex had no obvious changes co...
Understanding formation of organo-mineral association is crucial for soil organic matter (SOM) stabilization. To remove reactive minerals from un-disturbed natural soil (NS) and two cultivated soils (...
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The interaction of two or more substrates or ligands with the same binding site. The displacement of one by the other is used in quantitative and selective affinity measurements.
Water naturally or artificially infused with mineral salts or gases (carbon dioxide).
Americium. A completely man-made radioactive actinide with atomic symbol Am, atomic number 95, and atomic weight 243. Its valence can range from +3 to +6. Because of its nonmagnetic ground state, it is an excellent superconductor. It is also used in bone mineral analysis and as a radiation source for radiotherapy.
The direct struggle between individuals for environmental necessities or for a common goal.
An antigen solution emulsified in mineral oil. The complete form is made up of killed, dried mycobacteria, usually M. tuberculosis, suspended in the oil phase. It is effective in stimulating cell-mediated immunity (IMMUNITY, CELLULAR) and potentiates the production of certain IMMUNOGLOBULINS in some animals. The incomplete form does not contain mycobacteria.
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