Vinyl Fluorides: Competent Olefinic Counterparts in the Intramolecular Pauson-Khand Reaction.

08:00 EDT 29th March 2019 | BioPortfolio

Summary of "Vinyl Fluorides: Competent Olefinic Counterparts in the Intramolecular Pauson-Khand Reaction."

Despite the great advances achieved in the Pauson-Khand reaction and the ever-increasing demand for fluorinated compounds, the use of vinyl fluorides as olefinic counterparts in the above-mentioned transformation had been completely overlooked. Herein, we describe, for the first time, the intramolecular Pauson-Khand reaction of enynes containing a vinyl fluoride moiety.


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This article was published in the following journal.

Name: Organic letters
ISSN: 1523-7052


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Medical and Biotech [MESH] Definitions

Fluorides, usually in pastes or gels, used for topical application to reduce the incidence of DENTAL CARIES.

Inorganic fluorides of tin. They include both stannic fluoride (tin tetrafluoride) and stannous fluoride (tin difluoride). The latter is used in the prevention of dental caries.

Compounds containing the vinyl (-C=CH2) functional group.

A nonmetallic, diatomic gas that is a trace element and member of the halogen family. It is used in dentistry as flouride (FLUORIDES) to prevent dental caries.

POLYMERS derived from the monomer VINYL COMPOUNDS.

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