BaB2O3F2: A New Barium Fluorooxoborate with a Unique (_"∞" ^"2" )"B2O3F-" Layer and Short Cutoff Edge.

08:00 EDT 1st April 2019 | BioPortfolio

Summary of "BaB2O3F2: A New Barium Fluorooxoborate with a Unique (_"∞" ^"2" )"B2O3F-" Layer and Short Cutoff Edge."

The substitution of oxygen by fluorine in borate group offers a brand new materials platform from which intriguing structure and functionality may arise. Here, we report a new fluorooxoborate, BaB2O3F2, synthesized by introducing the F atoms into the BaO-B2O3 system. BaB2O3F2 exhibits a unique oxyfluoride layer (_"∞" ^"2" )"[B2O3F]-" and a deep-ultraviolet cutoff edge below 180 nm. The effect of the introduction of F atoms on the structure and optical property has been investigated which should be useful to further expand the borate chemistry and materials.


Journal Details

This article was published in the following journal.

Name: Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765


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