Flexidentate Coordination Behavior and Chemical Non-Innocence of a Bis(1,3-Diphosphacyclobutadiene) Sandwich Anion.

08:00 EDT 2nd April 2019 | BioPortfolio

Summary of "Flexidentate Coordination Behavior and Chemical Non-Innocence of a Bis(1,3-Diphosphacyclobutadiene) Sandwich Anion."

The homoleptic 1,3-diphosphacyclobutadiene sandwich complex [Co(η4-1,3-P2C2tBu2)2]- behaves as a versatile and highly flexible metalloligand toward Ni2+, Ru2+, Rh+, and Pd2+ cations, forming a range of unusual oligonuclear compounds.


Journal Details

This article was published in the following journal.

Name: Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765


DeepDyve research library

PubMed Articles [12113 Associated PubMed Articles listed on BioPortfolio]

1,3-Diphosphacyclobutene Cobalt Complexes.

The synthesis and characterization of rare 1,3-diphosphacyclobutene transition metal complexes is described. Reacting the cobalt hydride complex [Co(P2C2tBu2)2H] with nBuLi, tBuLi, and PhLi afford [Li...

Lanthanidocenes: Synthesis, Structure and Bonding of Linear Sandwich Complexes of Lanthanides.

The article presents the synthesis, structure, and bonding of a series of neutral and linear sandwich compounds with the cyclononatetraenyl (Cnt) ligand and divalent lanthanides. These compounds accou...

Hemiporphyrazine-Involved Sandwich Dysprosium Double-Decker Single-Ion Magnets.

Both heteroleptic (phthalocyaninato)(hemiporphyrazinato) and homoleptic bis(hemiporphyrazinato) dysprosium double-decker complexes, Dy[H(Hp)] (1) and Dy[H(Pc)(Hp)] (2) (HPc = metal-free phthalocyanine...

Supramolecular topology design of silver(i) and copper(ii) coordination polymers through a new semi-rigid sulfonyl ligand with different anion templates.

A series of metal organic coordination polymers (MOCPs) of silver(i) and copper(ii) coordinated with a novel multifunctional semi-rigid sulfonyl ligand with different anion templates and oxidation sta...

Reversible dielectric switching behavior of a 1D coordination polymer induced by photo and thermal irradiation.

Solvothermal reaction of Zn(NO3)2 with 2,9-bis-(2-pyridine-3-yl-vinyl)-[1,10]phenanthroline (3-bpep) and furan-2,5-dicarboxylic acid (2,5-H2FDC) afforded a one-dimensional (1D) coordination polymer {[...

Clinical Trials [2819 Associated Clinical Trials listed on BioPortfolio]

"Sandwich" Chemotherapy With Radiotherapy in Newly Diagnosed, Stage IE to IIE, ENKTL

A phase 2 study was conducted of "sandwich" protocols, with earlier RT after an initial 2 of P-CHOP (Pegaspargase, cyclophosphamide,vincristine, doxorubicin and dexamethasone ), followed b...

Effect of Strength and Coordination Training on Biomechanics and Injury in New Runners

The investigators hypothesize that new runners participating in an 8 week strength and coordination training program prior to beginning to run will 1) display different coordination patter...

Practices and Organizations Related to Emerging Occupations of Care (EPOCK) Coordination in Oncology

Several stakeholders are implied in cancer care pathways and there is a need for coordinating their actions. New occupations of care coordination have thus emerged. However, the conditions...

Histologic Evaluation of Bone Formation After Alveolar Augmentation by "Sandwich Osteotomy" Procedure for Dental Implants Insertion

The purpose of this study is to evaluate histologic bone remodeling after interpositional bone graft ("sandwich osteotomy" technique) using xenograft to fill the gap of the bone after movi...

Proprioception and Eye-head Coordination for the Cervical Spine

Specific aims of this project were as follows: 1. To investigate the eye-head coordination of patients with cervical spine degeneration. 2. To investigate the relationship of these i...

Medical and Biotech [MESH] Definitions

Any enhancement of a motivated behavior in which individuals do the same thing with some degree of mutual stimulation and consequent coordination.

An inhibitor of anion conductance including band 3-mediated anion transport.

Theoretical representations that simulate the behavior or activity of chemical processes or phenomena; includes the use of mathematical equations, computers, and other electronic equipment.

Neutral or negatively charged ligands bonded to metal cations or neutral atoms. The number of ligand atoms to which the metal center is directly bonded is the metal cation's coordination number, and this number is always greater than the regular valence or oxidation number of the metal. A coordination complex can be negative, neutral, or positively charged.

Chemical substances excreted by humans that elicit behavior or physiological responses from other humans. Perception of these chemical signals may be olfactory or by contact.

Quick Search


DeepDyve research library

Searches Linking to this Article