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An efficient Cu(ii)-catalyzed, C-H alkylation of BODIPY with a variety of alkyl diacyl peroxides has been developed for the first time, providing a late-stage and straightforward method for controllable synthesis of monoalkylated and dialkylated BODIPYs via a radical process that otherwise is difficult to obtain by literature methods. This chemo- and site-selective transformation will allow for the introduction of a variety of functionalities on the BODIPY core for highly versatile tethering to receptors and to other molecules of interest.
This article was published in the following journal.
Name: Chemical communications (Cambridge, England)
As an important type of typical synthetic azo dyes, the use of sudan I-IV dyes has been of concern worldwide because of their wide applications and illegal addition into various foodstuffs, potentiall...
Hybrid meso BODIPY dyes are synthesized and their linear and non-linear optical properties are studied. Time-resolved fluorescence lifetime decay is found to be identical for all dyes irrespective of ...
A new family of water-soluble and bioconjugatable aza-BODIPY fluorophores was designed and synthesized using a boron- functionalization strategy. These dissymmetric bis-ammonium aza-BODIPY dyes presen...
Two new Re(I)bipyridyltricarbonyl chloride complexes, Re(BB3)(CO)Cl and Re(BB4)(CO)Cl, featuring BODIPY groups appended to the 5,5'- or 6,6'-positions of the bipyridine ligand, respectively, were synt...
An efficient transition-metal-free regioselective C-H/S-H cross-coupling of BODIPY with thiols has been developed for the first time, providing a new and more straightforward method for controllable s...
Hypotheses: (1)Wound healing during hospital stay will be equal between systems, (2)RNs will perceive the Versatile One (EZCare) system as easier to use, (3)Costs related to dressing chang...
The Straumann Bone Level Tapered (BLT) implant Ø 2.9 mm implant was developed to allow treatment of patients with single tooth gaps of small dimensions in the lateral and central incisor ...
Previous with methylene blue suggested that oral administration may be superior to conventional spray catheters. The main advantages claimed were better staining due to longer exposure to ...
The idiopathic macular hole, age-related disease, is a major cause of vision loss and affects at least two persons in 1000 after 40 years. This hole causes an acute decline linked to a ce...
The objective of this randomized controlled trial is to evaluate changes in marginal bone levels and soft tissue dimensions around implants placed with the IAI at different positions in re...
Senior professionals who provide guidance, direction and support to those persons desirous of improvement in academic positions, administrative positions or other career development situations.
A pyrrolo-quinoline having two adjacent keto-groups at the 4 and 5 positions and three acidic carboxyl groups. It is a coenzyme of some DEHYDROGENASES.
Orthodontic appliances, fixed or removable, used to maintain teeth in corrected positions during the period of functional adaptation following corrective treatment. These appliances are also used to maintain the positions of the teeth and jaws gained by orthodontic procedures. (From Zwemer, Boucher's Clinical Dental Terminology, 4th ed, p263)
Compounds that contain three methine groups. They are frequently used as cationic dyes used for differential staining of biological materials.
Benzene derivatives which are substituted with two nitro groups in the ortho, meta or para positions.