Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C-C coupling reaction.

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Summary of "Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C-C coupling reaction."

A 2D porous MOF, {[Cu(1,2,3-btc)(bpe)(H2O)]·H2O}n (1), has been synthesized using a mixed linker system. The structural determination showed non-coordinated carboxylate groups decorating the pore surface. The desolvated MOF (1a) with pendant carboxylate groups was used as a template for the stabilization of Pd nps (2-3 nm) and the resulting composite Pd(0)@1a showed efficient catalytic activity for the Suzuki-Miyaura C-C coupling reaction.


Journal Details

This article was published in the following journal.

Name: Dalton transactions (Cambridge, England : 2003)
ISSN: 1477-9234


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