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Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes.

08:00 EDT 12th April 2019 | BioPortfolio

Summary of "Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes."

A magnesium-catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been developed. The compatibility with many functional groups makes this magnesium catalyzed procedure attractive for late stage functionalization. Experimental mechanistic investigations and DFT calculations reveal insights into the reaction mechanism of the magnesium catalyzed protocol.

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This article was published in the following journal.

Name: Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
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