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Transformation of Metal-Organic Frameworks into Stable Organic Frameworks with Inherited Skeletons and Catalytic Properties.

08:00 EDT 12th April 2019 | BioPortfolio

Summary of "Transformation of Metal-Organic Frameworks into Stable Organic Frameworks with Inherited Skeletons and Catalytic Properties."

Metal-organic frameworks (MOFs) are an emerging class of porous materials with attractive properties; however, their practical applications are heavily hindered by the fragile nature. We report herein an effective strategy to transform fragile coordination bonds in MOFs into stable covalent organic bonds under mild annealing decarboxylative coupling reaction conditions, which results in highly stable organic framework materials. This strategy endows successfully inherit the intrinsic framework skeletons, porosity and properties of the parent MOFs in the daughter organic framework materials which exhibit excellent chemical stability under harsh catalytic conditions. Therefore, this work opens a new avenue to synthesize stable organic framework materials derived from MOFs for applications in different fields.

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This article was published in the following journal.

Name: Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
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