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Due to the terrific structural advantages displayed by Metal-Organic Frameworks (MOFs), integrating Valence Tautomerism (VT) systems within MOFs could be an effective strategy in order to break through the constraints associated with the traditional VT systems. Herein, we report the first successful integration of a VT system into a MOF termed VT-MOF-1. The structural characteristics of VT-MOF-1, such as di-nuclear cobalt-catechol clusters and solvent-accessible pores, are both innovative and novel, potentially yielding new vitality within VT field. In addition, VT-MOF-1 exhibits specific sensing behaviors responsive to temperature and different solvent molecules as n-butanol, tert-butanol and isopropanol. The entropy values and configurations of the solvent molecules were validated to be responsible for the tunable sensing behaviors.
This article was published in the following journal.
Name: Journal of the American Chemical Society
This work reports a facile one-step method for the fabricating FeO@Au/polydopamine sandwich-like core-shell nanostructure, in which the Au/polydopamine (Au/PDA) hybrid shell is obtained via an in situ...
Aerobic reaction of the ligand H2L1, 2-(2-phenylazo)-anilino-4,6-di-tert-butylphenol, CoCl2·6H2O and Et3N in MeOH under refluxing conditions produces, after work-up and recrystallization, black cryst...
Cu(I)-based materials are highly potential in various applications including selective CO adsorption, which is one of the most important raw materials for diverse carbon-based chemicals. The reduction...
Due to the limitations of the conventional metal oxide-based electrodes, studies on organic redox-active materials as alternative electrodes for secondary batteries are emerging. Nonetheless, the repo...
Reversible anionic (oxygen) redox in lithium-rich cathode oxides has been becoming a blooming research topic to further boost the energy density in lithium-ion batteries. There are numerous experiment...
Auto polymerizing poly methyl methacrylate (PMMA), and light initiated resin modified PMMAs, are commonly used for fabricating provisional restorations (PRs) during prosthetic treatment 1....
Plasma redox status is well known to alter with age but previously differences have only been reported for two specific redox couples; reduced and oxidized cysteine and reduced and oxidize...
The purpose of this study was to determine the influence of cast material on correction of congenital idiopathic clubfeet using the Ponseti method.
The aim of this study is to compare the surgical outcomes of conventional lymph node dissection with unconventional lymph node dissection during resection of Intrahepatic cholangiocarcinom...
The purpose of this study is to test the feasibility of the study protocol. The study protocol was designed to evaluate questions - "Do educational materials improve dual x-ray absorptiome...
Materials that add an electron to an element or compound, that is, decrease the positiveness of its valence. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed)
The transport of materials through a cell. It includes the uptake of materials by the cell (ENDOCYTOSIS), the movement of those materials through the cell, and the subsequent secretion of those materials (EXOCYTOSIS).
An interdisciplinary study of the microstructure and composition of various materials such as metals, semiconductors, ceramics, and polymers, in relation to their macromolecular physical and chemical properties. Materials science enables the custom creation of new materials with specific properties and uses.
Substances used to create an impression, or negative reproduction, of the teeth and dental arches. These materials include dental plasters and cements, metallic oxide pastes, silicone base materials, or elastomeric materials.
Materials placed inside a root canal for the purpose of obturating or sealing it. The materials may be gutta-percha, silver cones, paste mixtures, or other substances. (Dorland, 28th ed, p631 & Boucher's Clinical Dental Terminology, 4th ed, p187)