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Organocatalytic Synthesis of Sulfoximidoyl-Containing Carbamates from Sulfoximines and Morita-Baylis-Hillman Carbonates.

08:00 EDT 15th April 2019 | BioPortfolio

Summary of "Organocatalytic Synthesis of Sulfoximidoyl-Containing Carbamates from Sulfoximines and Morita-Baylis-Hillman Carbonates."

An unexpected substitution reaction providing sulfoximidoyl-containing carbamates was observed when Morita-Baylis-Hillman carbonates and NH-sulfoximines were mixed in acetonitrile at elevated temperature. Key ingredients were triethylamine and ortho-hydroxybenzoic acid, which both had to be present in catalytic quantities.

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Name: Organic letters
ISSN: 1523-7052
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