Highly proton-conductive zinc metal-organic framework based on nickel(II) porphyrinylphosphonate.

08:00 EDT 16th May 2019 | BioPortfolio

Summary of "Highly proton-conductive zinc metal-organic framework based on nickel(II) porphyrinylphosphonate."

The design of new solid-state proton-conducting materials, is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF (IPCE-1Ni), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55 × 10-3 S cm-1 at 75 °C and 80% relative humidity).


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This article was published in the following journal.

Name: Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765


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