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Organic-Inorganic Hybrid Gold Halide Perovskites: Structural Diversity via Cation Size.

08:00 EDT 16th May 2019 | BioPortfolio

Summary of "Organic-Inorganic Hybrid Gold Halide Perovskites: Structural Diversity via Cation Size."

Crystal structures of a series of organic-inorganic hybrid gold iodide perovskites, formulated as A2[AuII2][AuIIII4](A = methylammonium (MA) (1) and formamidinium (FA) (2)), A'2[I3]1-x[AuII2]x[AuIIII4](A' = imidazolium (IMD) (3), guanidinium (GUA) (4), dimethylammonium (DMA) (5), pyridinium (PY) (6), and piperizinium (PIP) (7)), systematically changed depending on the cation size. In addition, triiodide (I3-) ions were partly incorporated into the AuI2- sites of 3-7, whereas they were not incorporated into those of 1 and 2. Such a difference comes from the size of the organic cation. Optical absorption spectra showed characteristic intervalence charge-transfer bands from AuI to AuIII species, and the optical band gap increased as the size of the cation become larger.

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Name: Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
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Medical and Biotech [MESH] Definitions

Inorganic derivatives of ammonia by substitution of one or more hydrogen atoms with chlorine atoms or organic compounds with the general formulas R2NCl and RNCl2 (where R is an organic group).

Compounds derived from organic or inorganic acids in which at least one hydroxyl group is replaced by an –O-alkyl or other organic group. They can be represented by the structure formula RCOOR’ and are usually formed by the reaction between an acid and an alcohol with elimination of water.

Organic compounds that contain GOLD as an integral part of the molecule. Some are used as ANTIRHEUMATIC AGENTS. The term chrysotherapy derives from an ancient Greek term for gold.

Unstable isotopes of gold that decay or disintegrate emitting radiation. Au 185-196, 198-201, and 203 are radioactive gold isotopes.

Stable gold atoms that have the same atomic number as the element gold, but differ in atomic weight. Au-197 is a stable isotope.

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