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Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks.

08:00 EDT 25th July 2019 | BioPortfolio

Summary of "Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks."

Zirconium-based metal-organic frameworks (Zr-MOFs) based on nets such as , , , , and with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive net from 12-connected hexagonal-prismatic Zr nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).

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Name: Journal of the American Chemical Society
ISSN: 1520-5126
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