Track topics on Twitter Track topics that are important to you
Zirconium-based metal-organic frameworks (Zr-MOFs) based on nets such as , , , , and with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive net from 12-connected hexagonal-prismatic Zr nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).
This article was published in the following journal.
Name: Journal of the American Chemical Society
A sterically encumbering multidentate β-diketiminato ligand, L2 ( L2=[ArNC(tBu)CHC(tBu)NCH CH N(Me)CH CH NMe ] , Ar=2,6-iPr C H ), is reported in this study along with its coordination chemistry to ...
Active-site directed probes are powerful tools for studying the ubiquitin conjugation and deconjugation machinery. Branched ubiquitin chains have emerged as important proteasome-targeting signals for ...
To provide guidelines to accelerate the Haber-Bosch (HB) process for synthesis of ammonia from hydrogen and nitrogen, we used Quantum Mechanics (QM) to determine the reaction mechanism and free energy...
Pseudokinases are members of the protein kinase superfamily but signal primarily through noncatalytic mechanisms. Many pseudokinases contribute to the pathologies of human diseases, yet they remain la...
The synthesis of aluminum complexes with redox-active formazanate ligands is described. Salt metathesis using AlCl was shown to form a five-coordinate complex with two formazanate ligands, whereas org...
To evaluate the efficacy of two different doses (5 and 10 g) of ZS orally administered once daily (qd) vs placebo in maintaining normokalemia in initially hyperkalemic patients having achi...
This is an international, multicentre, parallel-group, randomised, double-blind, placebo controlled, phase II study to evaluate the benefits and risks of using sodium zirconium cyclosilica...
A Randomized controlled Clinical trial including 96 patients in which aim is to investigate the clinical outcome of dental implants in titanium-zirconium alloy compared to traditional tita...
This is a single center, inpatient, open label pharmacodynamic study to determine the effect of 5 g and 10 g doses of Sodium Zirconium Cyclosilicate (ZS) administered once daily (qd) for 4...
The purpose of this study is to evaluate the efficacy of ZS in the treatment of hyperkalemia in patients on hemodialysis.
Zirconium. A rather rare metallic element, atomic number 40, atomic weight 91.22, symbol Zr. (From Dorland, 28th ed)
Catalytically active enzymes that are formed by the combination of an apoenzyme (APOENZYMES) and its appropriate cofactors and prosthetic groups.
A long pro-domain caspase that has specificity for the precursor form of INTERLEUKIN-1BETA. It plays a role in INFLAMMATION by catalytically converting the inactive forms of CYTOKINES such as interleukin-1beta to their active, secreted form. Caspase 1 is referred as interleukin-1beta converting enzyme and is frequently abbreviated ICE.
The midbrain portion of the reticular formation located in the MIDBRAIN TEGMENTUM.
A transmembrane-protein belonging to the TNF family of intercellular signaling proteins. It is a widely expressed ligand that activates APOPTOSIS by binding to TNF-RELATED APOPTOSIS-INDUCING LIGAND RECEPTORS. The membrane-bound form of the protein can be cleaved by specific CYSTEINE ENDOPEPTIDASES to form a soluble ligand form.