Synthesis of an Emissive Spectacle-Shaped Hexanuclear Rhenium(I) Complex.

08:00 EDT 9th September 2019 | BioPortfolio

Summary of "Synthesis of an Emissive Spectacle-Shaped Hexanuclear Rhenium(I) Complex."

Ring-shaped multinuclear Re(I) complexes (Re(I) rings) have the potential to function as useful units in multifarious photofunctional compounds because of their flexibility in molecular design and various photofunctions. The first synthetic example of the coupling reaction using a Re(I) ring as a building block to synthesize a novel spectacle-shaped hexanuclear complex is reported herein. This complex shows an efficient intramolecular energy transfer to accumulate the excitation energy into the central Re(I) units, and has suitable photophysical properties as a photosensitizer.


Journal Details

This article was published in the following journal.

Name: Inorganic chemistry
ISSN: 1520-510X


DeepDyve research library

PubMed Articles [6571 Associated PubMed Articles listed on BioPortfolio]

Rhenium-Catalyzed Phthalide Synthesis from Benzamides and Aldehydes via C-H Bond Activation.

The [4 + 1] annulation of benzamides and aldehydes for phthalide synthesis was achieved via rhenium-catalyzed C-H activation, which demonstrates an unprecedented reaction pattern distinct from those o...

Heterogeneous Aqueous CO Reduction Using a Pyrene-Modified Rhenium(I) Diimine Complex.

The development of molecular catalysts and materials that can convert carbon dioxide (CO) into a value-added product is a great chemical challenge. Molecular catalysts set benchmarks in catalyst inves...

H Activation and Direct Access to Terminal Nitride and -P Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate.

The rhenium(II) complex Re(η-Cp)(BDI) (; BDI = ,'-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate; Cp = cyclopentadienyl) was subjected to a number of reactivity studies that highlight its un...

Rhenium-Catalyzed Cyclization via 1,2-Iodine and 1,5-Hydrogen Migration for the Synthesis of 2-Iodo-1-indenes.

A rhenium complex catalyzed the formation of 2-iodo-1-indene derivatives through iodine and hydrogen migration of 3-iodopropargyl ethers. The reaction proceeded via generation of 1-iodoalkenylrhenium ...

Visual impairment and spectacle use in university students in central China: The Anyang University Students Eye Study.

To investigate the prevalence and associations of visual impairment and the spectacle use in university students in central China.

Clinical Trials [1118 Associated Clinical Trials listed on BioPortfolio]

Rhenium Re 188 P2045 in Patients With Lung Cancer Who Have Received or Refused to Receive Prior Chemotherapy

The purpose of this study is to determine the maximum dose that is safely tolerated of the experimental drug Rhenium Re 188 P2045. This will be done by first treating patients at relative...

Rhenium-188-HEDP vs. Radium-223-chloride in Patients With Advanced Prostate Cancer Refractory to Hormonal Therapy

Radium-223 chloride is an alpha-emitting radiopharmaceutical with proven survival benefit in patients with castration-resistant prostate cancer metastatic to bone. Beta-emitting radiopharm...

Tolerability of a Novel Spectacle Design With Reduced Peripheral Contrast

Prospective, randomized, subject-masked 3-arm clinical study to assess the pediatric acceptability across three iterations of a novel spectacle lens design.

Control of Myopia Using Novel Spectacle Lens Designs

Randomized, controlled, multisite, subject-and observer-masked, 3-arm parallel group clinical trial of 36-month duration to evaluate the safety and efficacy of a novel spectacle lens desig...

Spectacle Tints and Thin-Films for Migraine

Nearly all migraine sufferers report sensitivity to light during a headache and a significant proportion of sufferers report light sensitivity between attacks. Light is also a common trigg...

Medical and Biotech [MESH] Definitions

Rhenium. A metal, atomic number 75, atomic weight 186.2, symbol Re. (Dorland, 28th ed)

Complex compounds in which a dumbbell shaped molecule is encircled by a macrocycle. They are named after rota (wheel) and axis (axle). Notation with a prefix is used to indicate the number of interlocked components. They have potential use in NANOTECHNOLOGY. Rotaxanes have been made with CYCLODEXTRINS and CYCLIC ETHERS.

A genus of gram-negative, rod-shaped bacteria in the family ENTEROBACTERIACEAE. They exist only as primary endosymbionts of five species of TSETSE FLIES, found in specialized organelles called mycetomes. The bacteria supply crucial B vitamins (VITAMIN B COMPLEX) which the flies require for fertility.

A family of medium adaptin protein subunits of approximately 45 KDa in size. They have been primarily found as components of ADAPTOR PROTEIN COMPLEX 3 and ADAPTOR PROTEIN COMPLEX 4.

The coenzyme form of Vitamin B1 present in many animal tissues. It is a required intermediate in the PYRUVATE DEHYDROGENASE COMPLEX and the KETOGLUTARATE DEHYDROGENASE COMPLEX.

Quick Search

DeepDyve research library

Searches Linking to this Article