Production of xylose, levulinic acid, and lignin from spent aromatic biomass with a recyclable Brønsted acid synthesized from d-limonene as renewable feedstock from citrus waste.

08:00 EDT 4th September 2019 | BioPortfolio

Summary of "Production of xylose, levulinic acid, and lignin from spent aromatic biomass with a recyclable Brønsted acid synthesized from d-limonene as renewable feedstock from citrus waste."

This work aimed to develop a green protocol for chemical processing of spent aromatic biomass to obtain xylose, levulinic acid, and lignin in good yields via treatment with p-cymene-2-sulphonic acid (p-CSA), a Brønsted acid synthesised from d-limonene as a renewable feedstock from citrus waste. Chemical processing of palmarosa biomass with p-CSA under heating in an autoclave resulted in hydrolysate containing xylose (~16% yield). Further processing of pre-treated biomass with p-CSA in presence of aq. HCl under refluxing caused a selective degradation of cellulose to levulinic acid (~22% yield with respect to biomass). The residual biomass was used to afford lignin in good yields.


Journal Details

This article was published in the following journal.

Name: Bioresource technology
ISSN: 1873-2976
Pages: 122105


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Medical and Biotech [MESH] Definitions

The most abundant natural aromatic organic polymer found in all vascular plants. Lignin together with cellulose and hemicellulose are the major cell wall components of the fibers of all wood and grass species. Lignin is composed of coniferyl, p-coumaryl, and sinapyl alcohols in varying ratios in different plant species. (From Merck Index, 11th ed)

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