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Rhodium(I) Pincer Complexes of Nitrous Oxide.

08:00 EDT 12th September 2019 | BioPortfolio

Summary of "Rhodium(I) Pincer Complexes of Nitrous Oxide."

The synthesis of two well-defined rhodium(I) complexes of nitrous oxide (N O) is reported. These normally elusive adducts are stable in the solid state and persist in solution at ambient temperature, enabling comprehensive structural interrogation by N NMR and IR spectroscopy, and single-crystal X-ray diffraction. These methods evidence coordination of N O through the terminal nitrogen atom in a linear fashion and are supplemented by a computational energy decomposition analysis, which provides further insights into the nature of the Rh-N O interaction.

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This article was published in the following journal.

Name: Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
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Medical and Biotech [MESH] Definitions

Nitrogen oxide (N2O). A colorless, odorless gas that is used as an anesthetic and analgesic. High concentrations cause a narcotic effect and may replace oxygen, causing death by asphyxia. It is also used as a food aerosol in the preparation of whipping cream.

Rhodium. A hard and rare metal of the platinum group, atomic number 45, atomic weight 102.905, symbol Rh. (Dorland, 28th ed)

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