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Accessing 1,2-Substituted Cyclobutanes through 1,2-Azaborine Photoisomerization.

08:00 EDT 11th October 2019 | BioPortfolio

Summary of "Accessing 1,2-Substituted Cyclobutanes through 1,2-Azaborine Photoisomerization."

We provide a seminal example of the utility of the 1,2-azaborine motif as a 4C+1N+1B synthon in organic synthesis. Specifically, conditions for practically scalable 1,2-azaborine photoisomerization in a flow reactor are reported to furnish aminoborylated cyclobutane derivatives. C-B bond functionalizations to furnish a diverse set of highly substituted cyclobutanes were also achieved.

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Name: Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
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