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Enantioselective aryl-aryl coupling facilitated by chiral binuclear gold complexes.

08:00 EDT 11th October 2019 | BioPortfolio

Summary of "Enantioselective aryl-aryl coupling facilitated by chiral binuclear gold complexes."

Herein, we report stoichiometric investigations embodying the first highly enantioselective aryl-aryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp2)-C(sp2) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed aryl-aryl coupling reactions.

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Name: Chemical communications (Cambridge, England)
ISSN: 1364-548X
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Aryl CYCLOPENTANES that are a reduced (protonated) form of INDENES.

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