Kinetic modeling study on the combustion treatment of cathode from spent lithium-ion batteries.

08:00 EDT 11th October 2019 | BioPortfolio

Summary of "Kinetic modeling study on the combustion treatment of cathode from spent lithium-ion batteries."

Thermal treatment offers an alternative method for the separation of aluminum foil and cathode materials during spent lithium-ion batteries recycling. In this work, the combustion kinetic of cathode was studied based on six model-free (isoconversional) methods, namely Flynn-Wall-Ozawa (FWO), Friedman, Kissinger-Akahira-Sunose, Starink, Tang, and Boswell methods. The possible decomposition mechanism was also probed using a master-plots method (Criado method). Thermogravimetric analysis showed that the whole thermal process could be divided into three stages with temperatures of 37-578°C, 578-849°C, and 849-1000°C. The activation energy () derived from these model-free methods displayed the same trend, gradually increasing with a conversion range of 0.002-0.013, and significantly elevating beyond this range. The coefficients from the FWO method were larger, and the resulted fell into the range of 10.992-40.298 kJ/mol with an average value of 20.228 kJ/mol. Comparing the theoretical master plots with an experimental curve, the thermal decomposition of cathode could be better described by the geometric contraction models.


Journal Details

This article was published in the following journal.

Name: Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA
ISSN: 1096-3669
Pages: 734242X19879224


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