Nickel-Catalyzed Synthesis of Silanes from Silyl Ketones.

07:00 EST 8th November 2019 | BioPortfolio

Summary of "Nickel-Catalyzed Synthesis of Silanes from Silyl Ketones."

An unprecedented nickel-catalyzed decarbonylative silylation via CO extrusion intramolecular recombination fragment coupling of unstrained and nondirecting group-assisted silyl ketones is described. The inexpensive and readily available catalyst performs under mild reaction conditions and enables the synthesis of structurally diverse arylsilanes, including heterocyclic and natural product derivatives.


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Name: Organic letters
ISSN: 1523-7052


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