A Solvent Free Synthetic Route for Cerium(IV) Metal-Organic Frameworks with UiO-66 Architecture and Their Photocatalytic Application.

07:00 EST 8th November 2019 | BioPortfolio

Summary of "A Solvent Free Synthetic Route for Cerium(IV) Metal-Organic Frameworks with UiO-66 Architecture and Their Photocatalytic Application."

A near solvent-free synthetic route for Ce-UiO-66 metal-organic frameworks (MOFs) is presented. The MOFs are obtained by simply grinding the reagents, cerium ammonium nitrate (CAN) and the carboxylic linkers, in a mortar for few minutes with the addition of a small amount of acetic acid (AcOH) as modulator (8.75 eq, o.5 mL). The slurry is then transferred into a 2 mL vial and heated at 120 °C for 1 day. The MOFs have been characterized for their composition, crystallinity and porosity and employed as heterogeneous catalysts for the photo-oxidation reaction of substituted benzylic alcohols to benzaldaldehydes under near ultraviolet light irradiation. The catalytic performances, such as selectivity, conversion and kinetics, exceed those of similar systems studied by chemical oxidation using similar Ce-MOFs as catalyst. Moreover, the MOFs were found to be reusable up to three cycles without loss of activity. Density functional theory (DFT) calculations were used in order to fully describe the electronic structure of the best performing MOFs and to provide useful information on the catalytic activity experimentally observed.


Journal Details

This article was published in the following journal.

Name: ACS applied materials & interfaces
ISSN: 1944-8252


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Medical and Biotech [MESH] Definitions

Supramolecular networks that consist of ordered arrangements of organic electron donor linkers (usually ditopic or polytopic organic carboxylates) and metal cations. They can have an extremely high surface area and adjustable pore size that allows for the insertion of other molecules capable of various functions such as catalysis, capture of carbon dioxide, and drug delivery.

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Unstable isotopes of cerium that decay or disintegrate emitting radiation. Ce atoms with atomic weights 132-135, 137, 139, and 141-148 are radioactive cerium isotopes.

A liquid resinous varnish solubilized in a volatile solvent which may be combined with a pigment. It forms a hard, glossy, and protective coating when applied to wood or metal.

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