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Low valent group 14 phosphinidenide complexes ({SIDipp}P)2M exhibit P-M pπ-pπ interaction (M = Ge, Sn, Pb).

07:00 EST 8th November 2019 | BioPortfolio

Summary of "Low valent group 14 phosphinidenide complexes ({SIDipp}P)2M exhibit P-M pπ-pπ interaction (M = Ge, Sn, Pb)."

Herein we present the synthesis of novel low valent group 14 phosphinidenide complexes [({SIDipp}P)2M] exhibiting P-M pπ-pπ interactions (M = Ge, Sn, Pb), which were investigated by means of structural, spectroscopic and quantumchemical methods. Furthermore, the monosubstitued compounds [(SIDippP)MX]2 (M = Sn, X = Cl; M = Pb, X = Br) are presented, which show dimeric structures instead of multiple bonding interaction.

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This article was published in the following journal.

Name: Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
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