An unprecedented {FeO(OH)(OAc)}{WO(OH)} cluster sandwiched in the tetravacant tungstophosphate.

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Summary of "An unprecedented {FeO(OH)(OAc)}{WO(OH)} cluster sandwiched in the tetravacant tungstophosphate."

A novel tungstophosphate H12Na4K3[{Fe5O5(OH)2(OAc)2}2{W2-O2(OH)}{P2W14O54}2]·36H2O (1) containing an unprecedented [{Fe5O5(OH)2(OAc)2}2{W2O2(OH)}] unit has been successfully obtained and characterized by IR, TGA, magnetic susceptibility measurements and single-crystal X-ray diffraction. It shows a decameric FeIII molecular assembly formed through two {Fe5O23} subunits bridged by a {W2O3} motif.


Journal Details

This article was published in the following journal.

Name: Dalton transactions (Cambridge, England : 2003)
ISSN: 1477-9234


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