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Structurally Isomerized Bis-Biphenyl Moieties Embedded in Hexaphyrin(3.1.1.3.1.1) and Octaphyrin(1.1.1.0.1.1.1.0).

07:00 EST 14th January 2020 | BioPortfolio

Summary of "Structurally Isomerized Bis-Biphenyl Moieties Embedded in Hexaphyrin(3.1.1.3.1.1) and Octaphyrin(1.1.1.0.1.1.1.0)."

An --biphenyl moiety-incorporated 32π hexaphyrin(3.1.1.3.1.1) is successfully achieved. Replacing with connectivity in the biphenyl unit of hexaphyrin leads to the formation of its structural isomer, octaphyrin(1.1.1.0.1.1.1.0). Spectral and structural analyses reveal the lack of planarity in hexaphyrin and the presence of an -arene unit in octaphyrin, thus affording nonaromatic characteristics.

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This article was published in the following journal.

Name: Organic letters
ISSN: 1523-7052
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