Topics

Non-oxidative methane coupling over silica versus silica-supported iron(II) single sites.

08:00 EDT 10th March 2020 | BioPortfolio

Summary of "Non-oxidative methane coupling over silica versus silica-supported iron(II) single sites."

Non-oxidative CH 4 coupling is promoted by silica with incorporated iron sites, but the role of these sites and their speciation under reaction conditions are poorly understood. Here, silica-supported iron(II) single sites, prepared via surface organometallic chemistry and stable at 1020 °C in vacuum, are shown to rapidly initiate CH 4 coupling at 1000 °C, leading to 15-22% hydrocarbons selectivity at 3-4% conversion. During this process, iron reduces and forms carburized iron(0) nanoparticles. This reactivity contrasts with what is observed for (iron-free) partially dehydroxylated silica, that readily converts methane, albeit with low hydrocarbon selectivity and after an induction period. This study supports that iron sites facilitate faster initiation of radical reactions and tame the surface reactivity.

Affiliation

Journal Details

This article was published in the following journal.

Name: Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Pages:

Links

DeepDyve research library

PubMed Articles [11357 Associated PubMed Articles listed on BioPortfolio]

Catalytic Non-Oxidative Coupling of Methane on TaO.

Mass-selected TaO cluster ions catalyze the transformation of methane in a gas-phase ion trap experiment via non-oxidative coupling into ethane and H, which is a prospective reaction for the generatio...

Inflammatory and oxidative stress biomarkers induced by silica exposure in crystal craftsmen.

Identification of biomarkers associated with the diagnosis and prognosis of silicosis would be highly advantageous in the clinical setting. The aim of this study is to evaluate inflammatory and oxidat...

Yb3+ doped gain guided index anti-guided fiber based on the nanoporous silica glass rod.

We report a heavily Yb3+/Al3+/B3+/F- co-doped high silica rod with a negative refractive index relative to pure silica. The high silica rod was fabricated from nanoporous silica rod by the glass phase...

Dumbbell-Like Silica Coated Gold Nanorods and their Plasmonic Properties.

Silica coated gold nanorods with dumbbell-like morphology allowing dual functionalization in an individual nanostructure have attracted great attention for applications such as sensing and biological ...

Coupling of a whispering gallery mode to a silicon chip with photonic crystal.

We demonstrate the efficient coupling (99.5%) of a silica whispering gallery mode microresonator directly with a silicon chip by using a silicon photonic crystal waveguide as a coupler. The efficient ...

Clinical Trials [4276 Associated Clinical Trials listed on BioPortfolio]

A Study to Investigate the Stain and Plaque Removal Capability of Two Experimental Potassium Nitrate Dentifrices

The purpose of this study is to determine whether spherical silica can achieve similar or greater extrinsic dental stain and plaque removal, in comparison to dentifrices containing higher ...

Efficacy of a Commercial Dentifrice Containing 10% High Cleaning Silica Base for Tooth Whitening

The objective of the present study was to compare the effects of a commercially available dentifrice containing 10% high cleaning silica base, versus a control dentifrice, containing norma...

Safety Evaluation of Porous Silica in Men

The aim of the present study was to determine whether oral dosing, up to 9 grams/day, of porous silica administered as a food additive can be used safely in normal weight and obese male hu...

Comparison Between Bioactive Silica Graft Plus Platelet Rich Fibrin and Only Platelet Rich Fibrin Graft in Intrabony Defects With Diabetes

Various regenerative procedures used for the treatment of intabony defects.The Aim of this study is to compare the treatment outcome of bioactive silica graft with platelet rich fibrin Vs ...

Evaluation of Nano-crystalline Hydroxyapatite Silica Gel in Management of Periodontal Intrabony Defects

A clinical and radiographic evaluation of Nano-crystalline hydroxyapatite silica gel in comparison with bone allograft and open flap debridement for management of periodontal intrabony def...

Medical and Biotech [MESH] Definitions

A non-crystalline form of silicon oxide that has absorptive properties. It is commonly used as a desiccating agent and as a stationary phase for CHROMATOGRAPHY. The fully hydrated form of silica gel has distinct properties and is referred to as SILICIC ACID.

A poly(dimethylsiloxane) which is a polymer of 200-350 units of dimethylsiloxane, along with added silica gel. It is used as an antiflatulent, surfactant, and ointment base.

The generic term for salts derived from silica or the silicic acids. They contain silicon, oxygen, and one or more metals, and may contain hydrogen. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 4th Ed)

A form of pneumoconiosis resulting from inhalation of dust containing crystalline form of SILICON DIOXIDE, usually in the form of quartz. Amorphous silica is relatively nontoxic.

Quick Search


DeepDyve research library

Searches Linking to this Article