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Mg ion-catalyzed polymerization of 1,3-dioxolane in battery electrolytes.

08:00 EDT 24th March 2020 | BioPortfolio

Summary of "Mg ion-catalyzed polymerization of 1,3-dioxolane in battery electrolytes."

Electrolyte salts with Mg2+ and Al3+ Lewis acidic cations demonstrate polymerization of 1,3-dioxolane. The speed and extent of the reaction depends on coordination of the anion with the Mg2+ cation catalyst. Weakly coordinating anions such as TFSI- aid faster polymerization while strongly coordinating anions such as ClO4- hinder the polymerization.

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Name: Chemical communications (Cambridge, England)
ISSN: 1364-548X
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