Lewis acid capping of a uranium(v) nitride via a uranium(iii) azide molecular square.

08:00 EDT 24th March 2020 | BioPortfolio

Summary of "Lewis acid capping of a uranium(v) nitride via a uranium(iii) azide molecular square."

Reaction of (CpiPr4)2UI with NaN3 resulted in formation of tetrameric uranium(iii) azide-bridged 'molecular square' [(CpiPr4)2U(μ-η1:η1-N3)]4 (1). Addition of B(C6F5)3 to 1 induced loss of N2 at room temperature, yielding the uranium(v) borane-capped nitrido (CpiPr4)2U(μ-N)B(C6F5)3 (2).


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This article was published in the following journal.

Name: Chemical communications (Cambridge, England)
ISSN: 1364-548X


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Medical and Biotech [MESH] Definitions

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