Dielectric interlayers for increasing the transparency of metal films for mid-infrared attenuated total reflection spectroscopy.

18:00 EST 20th December 2014 | BioPortfolio

Summary of "Dielectric interlayers for increasing the transparency of metal films for mid-infrared attenuated total reflection spectroscopy."

By depositing a continuous, thin metal film on a substrate coated with a mid-infrared (IR) transparent dielectric film that fulfils the role of an index-matching, anti-reflective coating for the metal, the transparency of the metal in the IR wavelength range can be significantly enhanced. This effect is used to yield enhanced absorption in attenuated total internal reflection infrared (ATR-IR) spectroscopy in the presence of continuous thin metal films. The main limitation of the ATR technique when using continuous metal films is the low transparency of metals, especially for infrared light. Computations and experiments show an enhancement in the absorbance of a sample in contact with the metal at certain wavenumbers when the dielectric interlayer is present. The realisation of the setup is the stratified system consisting of zinc selenide-germanium (~1 μm)-gold (40 nm and 20 nm) using the organic solvent acetonitrile as sample. Enhancement is stronger in s- than in p-polarisation. In s-polarisation, enhancement factors of up to 4 have been observed so far in experiments, but calculations show a route to higher enhancements. In addition to the increased absorption, the absorbance spectra show interference fringes which are due to a mismatch in the real part of the refractive index of the sample in contact with the metal film compared to a reference measurement.

Affiliation

Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Str. 1, 40237 Düsseldorf, Germany. m.reithmeier@mpie.de

Journal Details

This article was published in the following journal.

Name: Physical chemistry chemical physics : PCCP
ISSN: 1463-9084
Pages: 14798-803

Links

PubMed Articles [6791 Associated PubMed Articles listed on BioPortfolio]

Functionalized Graphene Nanoribbon Films as a Radiofrequency and Optically Transparent Material.

We report that conductive films made from hexadecylated graphene nanoribbons (HD-GNRs) can have high transparency to radiofrequency (RF) waves even at very high incident power density. Nanoscale-thick...

Effect of In/Al ratios on structural and optical properties of InAlN films grown on Si(100) by RF-MOMBE.

In x Al1-x N films were deposited on Si(100) substrate using metal-organic molecular beam epitaxy. We investigated the effect of the trimethylindium/trimethylaluminum (TMIn/TMAl) flow ratios on the st...

Controlling Dielectric and Relaxor-Ferroelectric Properties for Energy Storage by Tuning Pb0.92La0.08Zr0.52Ti0.48O3 Film Thickness.

The energy storage properties of Pb0.92La0.08Zr0.52Ti0.48O3 (PLZT) films grown via pulse laser deposition were evaluated at variable film thickness of 125, 250, 500, and 1000 nm. These films show high...

Full Range Dielectric Characteristics of Calcium Copper Titanate Thin Films Prepared by Continuous Composition-Spread Sputtering.

Perovskite CaCu3Ti4O12 has drawn a great attention for various electronic applications due to the giant dielectric property as well as a strong stability at a wide range of temperature. In this paper,...

Development of Fluorescent Film Sensors Based on Electropolymerization for Iron(III) Ion Detection.

Two electroactive materials, M1 and M2, are synthesized and their fluorescent electropolymerized (EP) films are prepared and used to detect metal ions. From the tested metal ions, M1 and M2 are demons...

Clinical Trials [412 Associated Clinical Trials listed on BioPortfolio]

Metal Ion Release From an FDA-Approved Metal-on-Metal Total Hip Replacement Implant

This is a multi-center, randomized study to compare blood and urine cobalt, chromium, and titanium ion levels of a metal-on-metal articular bearing coupled with two different head sizes to...

A Multicentre Trial to Compare Two Articulating Bearing Surfaces as Used in Cementless Primary Hip Arthroplasty

The aim of this study is to demonstrate the non-inferiority of the ceramic-on-metal articulation using large diameter bearings (38mm to 60mm) compared to the metal on metal articulation us...

Impact of Systemic Corticosteroid Therapy on Lens Transparency and Quantification of Lens Autofluorescence.

Corticosteroid therapy is usually regarded as a risk factor for the development of posterior subcapsular cataracts but prospective studies on this topic and accurate assessment of this pot...

A Clinical Evaluation of Metal Ion Release From Metal-on-Metal Cementless Total Hip Arthroplasty

A clinical Evaluation to determine metal ion release from 4th generation metal-on-metal hip articulating surfaces in cementless total hip arthroplasty.

Investigation of Systemic Metal Ion Concentration Following a Ceramic-on-Metal Total Hip Arthroplasty

This is a pilot study to compare systemic concentrations of cobalt and chromium in patients that have previously undergone total hip arthroplasties with ceramic on metal and metal on metal...

Medical and Biotech [MESH] Definitions

Projection of near-IR light (INFRARED RAYS), in the 700-1000 nm region, across an object in parallel beams to an array of sensitive photodetectors. This is repeated at various angles and a mathematical reconstruction provides three dimensional MEDICAL IMAGING of tissues. Based on the relative transparency of tissues to this spectra, it has been used to monitor local oxygenation, brain and joints.

A technique of measuring the dielectric properties of materials, which vary over a range of frequencies depending on the physical properties of the material. The technique involves measuring, over a range of frequencies, ELECTRICAL IMPEDANCE and phase shift of an electric field as it passes through the material.

Works consisting of nonfiction films and video designed to teach, instruct, or train. (From Moving Image Materials: Genre Terms, 1988)

Measurement of the regional temperature of the body or an organ by infrared sensing devices, based on self-emanating infrared radiation.

That portion of the electromagnetic spectrum usually sensed as heat. Infrared wavelengths are longer than those of visible light, extending into the microwave frequencies. They are used therapeutically as heat, and also to warm food in restaurants.

Search BioPortfolio:
Loading